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Item Discovery works by comparing the player's value of Item Discovery against the enemies chance to drop items. As an example, if a player has an Item Discovery of 100, and a Pale Tongue has a 1% drop rate, the players drop rate will be equal to 1%. If the Item Discovery is increased to 400 then the drop rate will increase to 4%
Therefore, maximizing Item Discovery is suggested during farming otherwise drop rates will drop quite far in between one another making a farming session exhausting.
A recommended farming strategy takes place at the end of a play through (before heading into a NG+). The player can respec his or her character to reflect 100 Luck followed by equipping the Crystal Sage's Rapier (note the dex/str requirement), while wearing the Symbol of Avarice and the Covetous Gold Serpent Ring. Following this guideline should bring a player to 350+ Item Discovery. Additionally, a player can consume a Rusted Coin to increase Item Discovery by 50 or a Rusted Gold Coin to increase Item Discovery by 100.